Phase relation of CaSO<Subscript>4</Subscript> at high pressure and temperature up to 90 GPa and 2300 K     

Taku Fujii  Hiroaki Ohfuji  Toru Inoue 《Physics and Chemistry of Minerals》2016,43(5):353-361

Calcium sulfate (CaSO₄), one of the major sulfate minerals in the Earth’s crust, is expected to play a major role in sulfur recycling into the deep mantle. Here, we investigated the crystal structure and phase relation of CaSO₄ up to ~90 GPa and 2300 K through a series of high-pressure experiments combined with in situ X-ray diffraction. CaSO₄ forms three thermodynamically stable polymorphs: anhydrite (stable below 3 GPa), monazite-type phase (stable between 3 and ~13 GPa) and barite-type phase (stable up to at least 93 GPa). Anhydrite to monazite-type phase transition is induced by pressure even at room temperature, while monazite- to barite-type transition requires heating at least to 1500 K at ~20 GPa. The barite-type phase cannot always be quenched from high temperature and is distorted to metastable AgMnO₄-type structure or another modified barite structure depending on pressure. We obtained the pressure–volume data and density of anhydrite, monazite- and barite-type phases and found that their densities are lower than those calculated from the PREM model in the studied P–T conditions. This suggests that CaSO₄ is gravitationally unstable in the mantle and fluid/melt phase into which sulfur dissolves and/or sulfate–sulfide speciation may play a major role in the sulfur recycling into the deep Earth.  相似文献   

Computer-aided design of bus route maps     

Yukio Sadahiro  Takahito Tanabe  Maxime Pierre  Koichi Fujii 《制图学和地理信息科学》2016,43(4):361-376

The bus route map is a diagram that aims to convey necessary information for map readers to find an appropriate way of moving from an origin to a destination. Design of bus route map is a complicated and time-consuming task that requires careful consideration of readability and aesthetics. This paper proposes a new computational method for designing bus route maps. The method helps us to reduce six types of undesirable elements in bus route maps, i.e., gap, shift, crossing, overlap, misalignment, and acute bend. The method consists of two phases: line layout phase determines the relative order of bus routes on each road segment and map layout phase calculates the actual position of bus routes drawn on a map. This paper applies the method to the design of bus route maps of Chiba City, Japan. The result supports the effectiveness of the method as well as reveals open topics for future research.  相似文献   

Geophysical analysis of zonal tidal signals in length of day   总被引：5，自引：0，他引：5  

Benjamin Fong Chao  James B. Merriam  Yoshiaki Tamura 《Geophysical Journal International》1995,122(3):765-775

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Characteristics of horizontal crustal deformation in Japan as deduced from frequency distribution of maximum shear strain rate     

Yoichiro Fujii 《Pure and Applied Geophysics》1995,144(1):19-37

In order to study characteristics of horizontal crustal strains, we divide the Japanese Islands into 14 tectonic provinces consistent with the suggestion given byMatsuda (1990). We calculate frequency distribution of strain rates using the results of the Precise Control Survey initiated by the Geographical Survey Institute in 1973. This survey is a revision of old first- and second-order triangulation networks by trilateration. The principal axes and principal strains inside all the geodetic triangles are deduced from the comparison of the old triangulation and the new trilateration networks. The maximum shear strain rates are calculated by dividing the accumulated strains with the time intervals. The frequency distribution of strain rates is counted for each tectonic province and for the entire Japanese Islands. It is proved that the maximum shear strain rate with highest frequency ranges from 0.10–0.15 microstrain/a for 4409 data in the Japanese Islands. The mean value of the strain rates throughout the Japanese Islands is deduced to be 0.18 microstrain/a. We also calculated a mean value of strain rates for each tectonic province. Comparison is made between mean geodetic strain rates in the provinces and Quaternary strain rates estimated by geomorphic data. It is found that 0.3–0.4 microstrain/a of the highest order strain rate is now prevailing in the Izu province, the south Fossa-Magna collision zone, and some special provinces along the eastern part of the Japan Sea coast.  相似文献   

Eigen oscillation of a fluid sphere and source mechanism of harmonic volcanic tremor     

Eisuke Fujita  Yoshiaki Ida  Jun Oikawa 《Journal of Volcanology and Geothermal Research》1995,69(3-4)

The eigen oscillation of a fluid sphere embedded in an infinite elastic medium is analyzed to understand the source mechanism of volcanic tremor that vibrates nearly monotonically and attenuates slowly. The dimensionless eigen frequencies of the sinusoidal oscillation are calculated in a complex form with the attenuation factor in its imaginary part for various combinations of the three parameters: the contrasts of P-wave velocity, density and rigidity between the fluid and the country rock. Eigen oscillations consist of a high attenuation mode with a rapidly decaying pulsive wave at a low frequency and infinite number of regular modes with slowly decaying vibrations. For regular modes, the frequency of oscillation obtained from the real part of an eigen value is distributed in approximately regular intervals while the attenuation factor from the imaginary part is almost constant independent of the mode. Each eigen frequency of regular and high attenuation modes is degenerated with two independent eigen functions describing different distributions of displacement, velocity and stress. The theory is applied to harmonic volcanic tremor observed at Kusatsu-Shirane Volcano, central Japan. Observed spectral peaks of the tremor are explained by the eigen frequencies and attenuation factors of several lowest regular modes if the spherical fluid oscillator has a radius of dozens of meters and a P-wave velocity of about several hundred meters per second.  相似文献   

Mesozoic radiolarians and radiolarian-bearing sequences in the circum-Pacific regions: A report of the symposium-'Radiolarians and Orogenic Belts'     

Atsushi  Matsuoka  Yoshiaki  Aita  Munasri  Koji  Wakita  Gaoping  Shen  Hiroshi  Ujilé  Katsuo  Sashida  Valentina S.  Vishnevskaya  Nkita Y.  Bragin Fabrice  Cordey 《Island Arc》1996,5(2):203-213

Abstract This paper contains extended abstracts of the seven papers presented at the symposium 'Radiolarians and Orogenic Belts' held at the seventh meeting of the International Association of Radiolarian Paleontologists (INTERRAD). Important results of the symposium include the following: (1) Upper Paleozoic and Mesozoic cherts are widely distributed within accretionary complexes in the circum-Pacific orogenic belt. Radiolarian dating reveals that long durations of chert sedimentation in a pelagic environment are recorded on both sides of Pacific-rim accretionary complexes (e.g. New Zealand, Japan, Russian Far East, Canadian Cordillera). (2) Triassic radiolarian faunas from New Zealand and the Omolon Massif, northeast Siberia are similar in composition and are characterized by the absence of typical Tethyan elements. This suggests that radiolarian faunal provincialism may have been established as early as the Triassic. High-latitude radiolarian taxa exhibit a bi-polar distribution pattern. (3) The Lower Triassic interval in chert dominant pelagic sequences is mechanically weaker than other levels and acted as a décollement in accretionary events. This lithologic. contrast in physical property is considered to reflect radiolarian evolution, such as the end-Permian mass extinction.  相似文献   

Thermal diffusivity of lunar rocks under atmospheric and vacuum conditions     

Naoyuki Fujii  Masahiro Osako 《Earth and Planetary Science Letters》1973,18(1):65-71

Thermal diffusivity, k, of three lunar rocks (10049 and 10069; Type A, Apollo 11 and 14311; Apollo 14) and a terrestrial basalt (alkaline olivine basalt, Oki-do?go, Japan) was measured under one atmosphere and in vacuum conditions (10^?3 ～ 10^?5 mmHg) in the temperature range from 85 to 850°K. The semi-empirical curve of k =A + B/T +CT³ is fitted to the data in each condition. The porosity of rocks strongly affects the thermal diffusivity at low temperature ( T ? 500°K) in vacuum condition. At 150°K, thermal diffusivity of lunar rocks with porosity of 5.5% (10049) and 11% (10069) at one atmosphere is about 1.7 and 3.2 times of that in vacuum, respectively. The difference between the values at one atmosphere and those in vacuum decreases as the temperature increases. Measurements of k should be made at gas pressures at least lower than 10^?3 mmHg to estimate the value under lunar surface conditions.  相似文献   

Effects of a kappa distribution function of electrons on incoherent scatter spectra   总被引：2，自引：0，他引：2  

S. Saito  F. R. E. Forme  S. C. Buchert  S. Nozawa  R. Fujii 《Annales Geophysicae》2000,18(9):1216-1223

In usual incoherent scatter data analysis, the plasma distribution function is assumed to be Maxwellian. In space plasmas, however, distribution functions with a high energy tail which can be well modeled by a generalized Lorentzian distribution function with spectral index kappa (kappa distribution) have been observed. We have theoretically calculated incoherent scatter spectra for a plasma that consists of electrons with kappa distribution function and ions with Maxwellian neglecting the effects of the magnetic field and collisions. The ion line spectra have a double-humped shape similar to those from a Maxwellian plasma. The electron temperatures are underestimated, however, by up to 40% when interpreted assuming Maxwellian distribution. Ion temperatures and electron densities are affected little. Accordingly, actual electron temperatures might be underestimated when an energy input maintaining a high energy tail exists. We have also calculated plasma lines with the kappa distribution function. They are enhanced in total strength, and the peak frequencies appear to be slightly shifted to the transmitter frequency compared to the peak frequencies for a Maxwellian distribution. The damping rate depends on the electron temperature. For lower electron temperatures, plasma lines for electrons with a distribution function are more strongly damped than for a Maxwellian distribution. For higher electron temperatures, however, they have a relatively sharp peak.  相似文献   

Mineralogical and geochemical study of a newly discovered mafic granulite, northwest China: Implications for tectonic evolution of the Altay Orogenic Belt   总被引：5，自引：0，他引：5  

Han-Lin  Chen  Zi-Long  Li  Shu-Feng  Yang  Chuan-Wan  Dong  Wen-Jiao  Xiao  Yoshiaki  Tainosho 《Island Arc》2006,15(1):210-222

Abstract A mafic granulite body was newly discovered in the Altay Orogenic Belt, northwest China. The rocks comprise a suite of coarse‐grained and fine‐grained granulites. Orthopyroxenes (hypersthenes) in the rocks have high X_Mg and low Al₂O₃ contents, whereas clinopyroxenes have low TiO₂ and Al₂O₃ contents. Amphiboles and biotites have a high Mg/(Mg + Fe²⁺) ratio and low contents of F and Cl. The peak metamorphic pressure–temperature (P–T) conditions are estimated as 750–780°C and 6–7 kbar, and retrograde P–T conditions are in the range of 590–620°C and 2.3–3.7 kbar, indicating significant decompression. Metamorphic reactions and P–T estimates define a clockwise P–T path. Geochemically, the rocks are high in Mg/(Mg + Fe) and Al₂O₃, depleted in U, Th, K and Rb, and characterized by light rare earth element enrichment and a weak positive Eu anomaly. The Altay mafic granulite shows depleted Nb, P and Ti contents in the mid‐oceanic ridge basalt normalized spider diagram. The geochemical characteristics suggest that the protolith of the Altay mafic granulite was calc‐alkaline basalt and andesite with an island‐arc affinity. The rock has a high ¹⁴³Nd/¹⁴⁴Nd ratio with ?Nd(0) > 0, indicating derivation from a mantle‐depleted source. In the present study, a two‐stage model for the evolution of the Altay mafic granulite is proposed: an early stage in which calc‐alkaline basalt and andesite with island‐arc affinity were subducted into a deeper level of the crust and subjected to granulite‐facies metamorphism generating the mafic granulite, followed by the later stage exhumation of the system into the upper crust by the late Paleozoic thrusting.  相似文献   

Lithological and physical properties of core samples from the Sagara oil field: Oil occurrence in Sagara core samples     

Satoshi  Hirano  Yoshiaki  Araki  Koji  Kameo  Hiroshi  Kitazato  Hideki  Wada 《Island Arc》2006,15(3):313-327

Abstract   A drilling and coring investigation of the Sagara oil field, central Honshu, Japan, was conducted to contribute to the understanding of hydrocarbon migration processes in a forearc basin. Core samples were analyzed to determine lithology, physical properties (specifically gas permeability) and the characteristics of oil occurrence. Gas permeability values greater than approximately 10⁻¹¹ m² constitute the basic precondition for any lithology to serve as a potential fluid conduit or reservoir in the Sagara oil field. Cores recovered from the 200.6-m-deep borehole were primarily composed of alternating siltstone, sandstone and conglomerate, all of which are correlated to the late Miocene Sagara Group. Both sandstone and conglomerate can be classified into two types, carbonate-cemented and poorly to non-cemented, based on matrix material characteristics. Oil stains are generally absent in the former lithology and more common in the latter. Variations in physical properties with respect to gas permeability values are directly related to the presence and character of carbonate cement, with higher permeabilities common in poorly to non-cemented rocks. The relationships between lithology, oil-staining, cementation and permeability indicate that cementation preceded oil infiltration and that cementation processes exerted significant control on the evolution of the reservoir.  相似文献